A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene-Reference-Cited by-同舟云学术

A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene

Published:2021 Issue:19 Volume:12 Page:2860-2867
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Yang Xuejin¹²³⁴^ORCID,Murphy Laura M.⁵⁶⁷⁸⁴,Haque Farihah M.¹⁹¹⁰⁴¹^ORCID,Grayson Scott M.¹⁹¹⁰⁴^ORCID,Boydston Andrew J.¹²³⁴¹¹^ORCID

Affiliation:

1. Department of Chemistry

2. University of Wisconsin-Madison

3. Madison

4. USA

5. Division of Sciences and Mathematics

6. School of Integrated Arts and Sciences

7. University of Washington Tacoma

8. Tacoma

9. Tulane University

10. New Orleans

11. Department of Chemical and Biological Engineering

Abstract

We have developed a highly efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP) and investigated the T_g–M_n dependence of linear pDCPD.

Funder

National Science Foundation

University of Wisconsin-Madison

Army Research Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00191D

Reference61 articles.

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2. Ring-opening metathesis polymerization of exo-dicyclopentadiene: Reversible crosslinking by a metathesis catalyst

3. Polymerization of Dicyclopentadiene: A Tale of Two Mechanisms

4. The polymerization of dicyclopentadiene: an investigation of mechanism

5. Structure of the Thermally Induced Cross-Link in C-Linked Methyl Ester-Functionalized Polydicyclopentadiene (fPDCPD)

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