Durable photoelectrochemical CO2 reduction with water oxidation using a visible-light driven molecular photocathode
Author:
Affiliation:
1. Department of Chemistry
2. School of Science
3. Tokyo Institute of Technology
4. Tokyo 152-8550
5. Japan
6. Department of Energy and Hydrocarbon Chemistry
7. Graduate School of Engineering
8. Kyoto University
9. Kyoto 615-8510
Abstract
A durable molecular photocathode driving CO2 reduction with over 1200 of turnover number was developed by electropolymerization of Ru(ii) complexes. The cell with a suitable photoanode enabled CO2 reduction with H2O oxidation with no bias for 24 h.
Funder
Core Research for Evolutional Science and Technology
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/TA/D0TA07351B
Reference41 articles.
1. Selective CO2 Conversion to Formate Conjugated with H2O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts
2. Solar-Driven Photocatalytic CO2 Reduction in Water Utilizing a Ruthenium Complex Catalyst on p-Type Fe2O3 with a Multiheterojunction
3. Z-Schematic and visible-light-driven CO2 reduction using H2O as an electron donor by a particulate mixture of a Ru-complex/(CuGa)1−xZn2xS2 hybrid catalyst, BiVO4 and an electron mediator
4. Photoelectrochemical CO2 reduction using a Ru(ii)–Re(i) multinuclear metal complex on a p-type semiconducting NiO electrode
5. Photoelectrochemical Reduction of CO2 Coupled to Water Oxidation Using a Photocathode with a Ru(II)–Re(I) Complex Photocatalyst and a CoOx/TaON Photoanode
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