An ultra-stable oxoiron(iv) complex and its blue conjugate base-Reference-Cited by-同舟云学术

An ultra-stable oxoiron(iv) complex and its blue conjugate base

Published:2014 Issue:3 Volume:5 Page:1204-1215
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

England Jason¹²³,Bigelow Jennifer O.¹²³,Van Heuvelen Katherine M.¹²³,Farquhar Erik R.¹²³,Martinho Marléne⁴⁵⁶,Meier Katlyn K.⁴⁵⁶,Frisch Jonathan R.¹²³,Münck Eckard⁴⁵⁶,Que Lawrence¹²³

Affiliation:

1. Department of Chemistry and Center for Metals in Biocatalysis

2. University of Minnesota

3. Minneapolis, USA

4. Department of Chemistry

5. Carnegie Mellon University

6. Pittsburgh, USA

Abstract

We report the first conjugate acid–base pair of nonheme oxoiron(iv) complexes, which are supported by a tetramethylcyclam ligand with a pendant amide that binds trans to the oxo group via the carbonyl oxygen.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC52755G

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