Umpolung coupling of pyridine-2-carboxaldehydes and propargylic carbonates via N-heterocyclic carbene/palladium synergetic catalysis-Reference-Cited by-同舟云学术

Umpolung coupling of pyridine-2-carboxaldehydes and propargylic carbonates via N-heterocyclic carbene/palladium synergetic catalysis

Published:2021 Issue:36 Volume:57 Page:4452-4455
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bi Weiyang¹²³⁴⁵,Yang Yunhui¹²³⁴⁵,Ye Song¹²³⁴⁵^ORCID,Wang Congyang¹²³⁴⁵^ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. CAS Key Laboratory of Molecular Recognition and Function

3. CAS Research/Education Center for Excellence in Molecular Sciences

4. Institute of Chemistry

5. Chinese Academy of Sciences

Abstract

The umpolung cross-coupling reaction of pyridine-2-carboxaldehydes and propargylic carbonates has been developed for the first time through N-heterocyclic carbene/palladium cooperative catalysis, giving the propargylic ketones regioselectively.

Funder

National Natural Science Foundation of China

Beijing Municipal Science and Technology Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01311D

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