Ligand exchange processes in zirconocene dichloride–trimethylaluminum bimetallic systems and their catalytic properties in reaction with alkenes

Author:

Parfenova Lyudmila V.123ORCID,Kovyazin Pavel V.123,Gabdrakhmanov Vener Z.123,Istomina Galina P.12345,Ivchenko Pavel V.67382,Nifant'ev Ilya E.67382ORCID,Khalilov Leonard M.123ORCID,Dzhemilev Usein M.123

Affiliation:

1. Institute of Petrochemistry and Catalysis

2. Russian Academy of Sciences

3. Russian Federation

4. Ufa State Petroleum Technical University

5. 450062 Ufa

6. Department of Chemistry

7. Lomonosov Moscow State University

8. A.V. Topchiev Institute of Petrochemical Synthesis

Abstract

The exchange processes in the system L2ZrCl2–(AlMe3)2 and its reactivity towards the alkene were studied.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference81 articles.

1. Metal complex catalysis in the synthesis of organoaluminium compounds

2. U. M. Dzhemilev and A. G.Ibragimov , in Modern Reduction Methods , ed. P. G. Andresson and J. J. Munslou , Wiley-VCH , Weinheim, Germany , 2008 , pp. 447–489

3. G. A. Tolstikov , U. M.Dzhemilev and A. G.Tolstikov , Aluminiyorganicheskie soedineniya v organicheskom sinteze (Organoaluminum compounds in organic synthesis) , Akad. izd. GEO , Novosibirsk , 2009 , 645 p. (in Russian)

4. Catalytic cyclometalation reaction of unsaturated compounds in synthesis of magnesa- and aluminacarbocycles

5. V. A. D'yakonov , Dzhemilev Reaction in Organic and Organometallic Synthesis (Chemistry Research and Applications) , Nova Science Pub Inc , NY , 2010 , 96 p

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