Highly selective conversion of phenol to cyclohexanol over Ru/Nb2O5-nC18PA catalysts with increased acidity in a biphasic system under mild conditions

Author:

Zhan Jiahui12,Hu Rui12,Luo Xi12,Zhang Cheng3,Luo Gang12,Fan Jiajun4ORCID,Clark James H.124ORCID,Zhang Shicheng12ORCID

Affiliation:

1. Shanghai Technical Service Platform for Pollution Control and Resource Utilization of Organic Wastes, Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai 200438, China

2. Shanghai Institute of Pollution Control and Ecological Security, Shanghai, 200092, China

3. College of Environmental and Resource Sciences, Zhejiang A&F University, Hangzhou 311300, China

4. Green Chemistry Centre of Excellence, Department of Chemistry, University of York, York, YO10 5DD, UK

Abstract

The catalytic activity was enhanced by the introduction of C18PA on the support of the Ru/Nb2O5 catalyst. The addition of more Lewis acid sites on the support activated the aromatic ring in phenol and promoted the formation of cyclohexanol.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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