Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters-Reference-Cited by-同舟云学术

Asymmetric organocatalytic synthesis of tertiary azomethyl alcohols: key intermediates towards azoxy compounds and α-hydroxy-β-amino esters

Published:2017 Issue:14 Volume:15 Page:2993-3005
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Carmona José A.¹²³,Gonzalo Gonzalo de⁴⁵⁶³,Serrano Inmaculada⁴⁵⁶³,Crespo-Peña Ana M.¹²³,Šimek Michal¹²³,Monge David⁴⁵⁶³,Fernández Rosario⁴⁵⁶³,Lassaletta José M.¹²³^ORCID

Affiliation:

1. Instituto de Investigaciones Químicas (CSIC-US) and Centro de Innovación en Química Avanzada (ORFEO-CINQA)

2. 41092 Sevilla

3. Spain

4. Departamento de Química Orgánica

5. Universidad de Sevilla and Centro de Innovación en Química Avanzada (ORFEO-CINQA)

6. 41012 Sevilla

Abstract

New carbohydrate based organocatalysts have been developed for the asymmetric nucleophilic addition of formaldehyde tert-butylhydrazone to α-keto esters.

Funder

Consejería Economía, Innovación, Ciencia y Empleo, Junta de Andalucia

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00308K

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