Waste-free and efficient hydrosilylation of olefins

Author:

Pandarus Valerica123ORCID,Ciriminna Rosaria4567ORCID,Gingras Geneviève123,Béland François123,Kaliaguine Serge89210ORCID,Pagliaro Mario4567ORCID

Affiliation:

1. SiliCycle

2. Quebec City

3. Canada G1P 4S6

4. Istituto per lo Studio dei Materiali Nanostrutturati

5. CNR

6. 90146 Palermo

7. Italy

8. Department of Chemical Engineering

9. Université Laval

10. Canada G1 V 0A6

Abstract

High purity silicone precursors can now be synthesized by hydrosilylation of solvent-free olefins catalyzed by a highly stable and active glass hybrid catalyst consisting of mesoporous organosilica microspheres doped with Pt nanoparticles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference43 articles.

1. S. J. Clarson , J. J.Fitzgerald , M. J.Owen , S. D.Smith and M. E.Van Dyke , Science and Technology of Silicones and Silicone-Modified Materials , American Chemical Society , Washington DC, USA and Oxford University Press, Oxford, 2007

2. The global market is estimated to reach a volume of around 3 million tonnes by 2022: Imarc Services Private Limited , Silicones Market: Global Industry Trends, Share, Size, Growth, Opportunity and Forecast 2017-2022 , Delhi , 2017

3. The Addition of Silicon Hydrides to Olefinic Double Bonds. Part II. The Use of Group VIII Metal Catalysts

4. Platinum-Based Heterogeneously Catalyzed Hydrosilylation

5. Umicore , New Catalysts for Hydrosilylation Reactions, http://pmc.umicore.com/storage/pmc/umicore-pmc-new-hs-catalysts.pdf

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