Long-range supramolecular synthon polymorphism: a case study of two new polymorphic cocrystals of Ph2Te2–1,4-C6F4I2-Reference-Cited by-同舟云学术

Long-range supramolecular synthon polymorphism: a case study of two new polymorphic cocrystals of Ph₂Te₂–1,4-C₆F₄I₂

Published:2022 Issue:7 Volume:24 Page:1442-1452
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Torubaev Yury V.¹^ORCID,Skabitsky Ivan V.¹,Anisimov Aleksei A.²,Ananyev Ivan V.¹^ORCID

Affiliation:

1. N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, GSP-1, Leninsky prospect, 31, 119991 Moscow, Russia

2. A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

Abstract

Two new polymorphic forms of Ph2Te2–1,4-C6F4I2 cocrystals feature an unusual packing of Ph2Te2 molecules, which is typical for native Ph2Se2 but not Ph2Te2. This suggests the existence the yet unknown, Ph2Se2-like polymorph of Ph2Te2.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D1CE01487K

Reference90 articles.

1. Control of Molecular Orientation in Organic Semiconductors Using Weak Iodine–Iodine Interactions

2. Modulation of Metallophilic and π–π Interactions in Platinum Cyclometalated Luminophores with Halogen Bonding

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4. A new supramolecular heterosynthon [C–I⋯OC(carboxylate)] at work: engineering copper acetate cocrystals

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