Why do silanes reduce electron-rich phosphine oxides faster than electron-poor phosphine oxides?-Reference-Cited by-同舟云学术

Why do silanes reduce electron-rich phosphine oxides faster than electron-poor phosphine oxides?

Published:2020 Issue:8 Volume:56 Page:1227-1230
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kirk Alicia M.¹²³^ORCID,O’Brien Christopher J.⁴⁵⁶^ORCID,Krenske Elizabeth H.¹²³^ORCID

Affiliation:

1. School of Chemistry and Molecular Biosciences

2. The University of Queensland

3. Australia

4. ChemTank Ltd

5. Runcorn

6. UK

Abstract

DFT calculations explain the counterintuitive phenomenon that silanes reduce electron-rich (alkyl) phosphine oxides faster than electron-poor (aryl) phosphine oxides.

Funder

Australian Research Council

University of Queensland

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08718D

Reference24 articles.

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2. Organophosphorus Catalysis to Bypass Phosphine Oxide Waste

3. The development of catalytic nucleophilic substitution reactions: challenges, progress and future directions

4. From phosphine-promoted to phosphine-catalyzed reactions by in situ phosphine oxide reduction

5. Recent advances in catalytic Wittig-type reactions based on P(III)/P(V) redox cycling

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