Inversion of donor–acceptor roles in photoinduced intervalence charge transfers-Reference-Cited by-同舟云学术

Inversion of donor–acceptor roles in photoinduced intervalence charge transfers

Published:2019 Issue:53 Volume:55 Page:7659-7662
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Aramburu-Trošelj Bruno M.¹²³⁴⁵^ORCID,Oviedo Paola S.¹²³⁴⁵,Ramírez-Wierzbicki Ivana¹²³⁴⁵^ORCID,Baraldo Luis M.¹²³⁴⁵^ORCID,Cadranel Alejandro¹²³⁴⁵^ORCID

Affiliation:

1. Universidad de Buenos Aires

2. Facultad de Ciencias Exactas y Naturales

3. Departamento de Química Inorgánica

4. Analítica y Química Física, Pabellón 2

5. Ciudad Universitaria

Abstract

Upon MLCT photoexcitation, {(tpy)Ru} becomes the electron acceptor in the mixed valence {(tpy˙⁻)Ru^III−δ-NC-M^II+δ} moiety, reversing its role as the electron donor in the ground-state mixed valence analogue.

Funder

Universidad de Buenos Aires

Consejo Nacional de Investigaciones Científicas y Técnicas

Agencia Nacional de Promoción Científica y Tecnológica

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC03483H

Reference50 articles.

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2. The Localized-to-Delocalized Transition in Mixed-Valence Chemistry

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4. Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium

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