Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex-Reference-Cited by-同舟云学术

Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

Published:2017 Issue:43 Volume:46 Page:14757-14761
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Whited Matthew T.¹²³⁴^ORCID,Zhang Jia¹²³⁴,Ma Senjie¹²³⁴,Nguyen Binh D.¹²³⁴,Janzen Daron E.⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Carleton College

3. Northfield

4. USA

5. Department of Chemistry and Biochemistry

6. St. Catherine University

7. St. Paul

Abstract

The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene [P₂Si]Ru complexes are reported. The base-free complex performs cooperative, silylene-assisted hydride transfer to CO₂ and CS₂.

Funder

American Chemical Society Petroleum Research Fund

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03659K

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5. Reactions of a Neutral Silylene Ruthenium Complex with Heterocumulenes: C═O Hydrosilylation of Isocyanates vs C═S Bond Cleavage of Isothiocyanate

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