Roaming as the dominant mechanism for molecular products in the photodissociation of large aliphatic aldehydes
Author:
Affiliation:
1. Department of Chemistry
2. National Chung Hsing University
3. Taichung 402
4. Taiwan
5. National Taiwan University
6. and Institute of Atomic and Molecular Sciences
7. Academia Sinica
8. Taipei 106
Abstract
Photodissociation of isobutyraldehyde (C3H7CHO) at 248 nm is investigated using time-resolved Fourier-transform infrared emission spectroscopy to demonstrate the growing importance of the roaming pathway with increasing molecular size of aliphatic aldehydes.
Funder
Ministry of Science and Technology, Taiwan
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP03408F
Reference42 articles.
1. The Roaming Atom: Straying from the Reaction Path in Formaldehyde Decomposition
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4. Roaming is the dominant mechanism for molecular products in acetaldehyde photodissociation
5. Imaging the molecular channel in acetaldehyde photodissociation: roaming and transition state mechanisms
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