Metalloid germanium cluster shears for lanthanide diiodides-Reference-Cited by-同舟云学术

Metalloid germanium cluster shears for lanthanide diiodides

Published:2023 Issue:15 Volume:52 Page:4669-4673
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Klementyeva Svetlana V.¹^ORCID,Schrenk Claudio¹^ORCID,Zhang Minghui²,Khusniyarov Marat M.²^ORCID

Affiliation:

1. Chemistry Department, University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

2. Department of Chemistry and Pharmacy, Friedrich-Alexander University Erlangen-Nürnberg (FAU), Egerlandstraße 1, 91058 Erlangen, Germany

Abstract

Three ionic compounds with metalloid germanium cluster [Ge9(Hyp)3]−as free anions and polynuclear divalent lanthanide-iodide cations have been obtained and structurally characterized. A blue luminescence of Eu2+was found.

Funder

China Scholarship Council

Friedrich-Alexander-Universität Erlangen-Nürnberg

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00578J

Reference53 articles.

1. Half‐Sandwich Complexes [Cp′ 4 Ln 4 I 8 ] 4 (Ln=Ce, Pr):Emergence of Donor‐Free Organolanthanide Nanowheels

2. Nanoscale Organolanthanum Clusters: Nuclearity‐Directing Role of Cyclopentadienyl and Halogenido Ligands

3. Novel, Highly Symmetrical Halogen-Centered Polynuclear Lanthanide Complexes: [Cp6Yb6Cl13]− and [Cp12Sm12Cl24]

4. Structural Diversity and Multielectron Reduction Reactivity of Samarium(II) Iodido-β-diketiminate Complexes Dependent on Tetrahydrofuran Content

5. Donor-Solvent-Dependent Cluster Formation of (C5Me5)SmI2(THF)x-Type Half-Sandwich Complexes

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