Ferrimagnetic and relaxor ferroelectric properties of R2MnMn(MnTi3)O12 perovskites with R = Nd, Eu, and Gd

Author:

Liu Ran12345,Tanaka Masahiko6784,Mori Hiromu91011124,Inaguma Yoshiyuki91011124ORCID,Yamaura Kazunari12345ORCID,Belik Alexei A.1234ORCID

Affiliation:

1. International Center for Materials Nanoarchitectonics (WPI-MANA)

2. National Institute for Materials Science (NIMS)

3. Tsukuba

4. Japan

5. Graduate School of Chemical Sciences and Engineering

6. Synchrotron X-ray Station at SPring-8

7. NIMS

8. Sayo-cho

9. Department of Chemistry

10. Faculty of Science

11. Gakushuin University

12. Tokyo 171-8588

Abstract

A-site columnar-ordered quadruple perovskites R2MnMn(MnTi3)O12 (R = Nd, Eu, Gd) exhibit relaxor-like ferroelectric properties and ferrimagnetic transitions with large moments.

Funder

Nippon Sheet Glass Foundation for Materials Science and Engineering

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Reference37 articles.

1. R. H. Mitchell , Perovskites: Modern and Ancient , Almaz Press , Thunder Bay, Ontario, Canada , 2002

2. A. M. Abakumov , A. A.Tsirlin and E. V.Antipov , Transition-Metal Perovskites , in Comprehensive Inorganic Chemistry II (Second Edition): From Elements to Applications , ed. J. Reedijk and K. R. Poeppelmeier , Elsevier , Amsterdam , 2013 , vol. 2, pp. 1–40

3. Oxides, Oxides, and More Oxides: High-κ Oxides, Ferroelectrics, Ferromagnetics, and Multiferroics

4. Reconfigurable ferromagnetic liquid droplets

5. Group-theoretical analysis of 1:3 A-site-ordered perovskite formation

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