Novel N(SCF<sub>3</sub>)(CF<sub>3</sub>)-amines: synthesis, scalability and stability-Reference-Cited by-同舟云学术

Novel N(SCF₃)(CF₃)-amines: synthesis, scalability and stability

Published:2023 Issue:14 Volume:14 Page:3893-3898
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yang Yi¹,Saffon-Merceron Nathalie²,Vantourout Julien C.¹^ORCID,Tlili Anis¹^ORCID

Affiliation:

1. Institute of Chemistry and Biochemistry (ICBMS–UMR CNRS 5246), Univ Lyon, Université Lyon 1, CNRS, CPE-Lyon, INSA, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne, France

2. Institut de Chimie de Toulouse (FR 2599), Université de Toulouse, CNRS, 118 Route de Narbonne, 31062 Toulouse, France

Abstract

We disclosed herein a straightforward strategy for the synthesis of unprecedentedN-((trifluoromethyl)thio),N-(trifluoromethyl) amines using a combination of isothiocyanates, a fluoride source and an electrophilic trifluoromethylthiolation reagent.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06542H

Reference47 articles.

1. P.Kirsch , Modern Fluoroorganic Chemistry , Wiley-VCH , Weinheim , 2013