Effect of solvent isomers on the gelation properties of tri-aryl amine organogels and their hybrid thermoreversible gels with poly[vinyl chloride]

Author:

Xiao Yao1,Dominique Collin1,Odile Gavat1,Alain Carvalho1,Emilie Moulin1ORCID,Nicolas Giuseppone1ORCID,Jean-Michel Guenet1ORCID

Affiliation:

1. Institut Charles Sadron CNRS-Université de Strasbourg 23 rue du Loess, BP84047 67034 STRASBOURG, Cedex2, France

Abstract

The gelation properties of tri-aryl amine (TATA) in two isomers of dichlorobenzene, namely ortho-dichlorobenzene (o-DCB) and meta-dichlorobenzene (m-DCB), have been studied by calorimetry for mapping out the temperature–concentration phase diagram.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Reference44 articles.

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2. In Molecular Gels: Materials with Self-Assembled Fibrillar Networks , ed. P. Terech and R. G. Weiss , Springer Verlag , 2006

3. The Past, Present, and Future of Molecular Gels. What Is the Status of the Field, and Where Is It Going?

4. J. M.Guenet , Organogels: thermodynamics, structure, solvent role and properties , Springer International Publishing , N.Y. , 2016 . According to the dictionary: a network is “ a large system of lines, tubes, wires, etc. that cross one another or are connected with one another ”

5. In Molecular Gels, Structure and Dynamics , ed., R. G. Weiss , Monograph in Supramolecular Chemistry , Royal Society of Chemistry , London , 2018

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