Structure-switching M3L2 Ir(iii) coordination cages with photo-isomerising azo-aromatic linkers
Author:
Affiliation:
1. School of Chemistry
2. University of Leeds
3. Woodhouse Lane
4. UK
5. Organic Semiconductor Centre
6. EaStCHEM School of Chemistry
7. University of St Andrews
8. St Andrews
Abstract
Deep-blue luminescent [{Ir(C^N)2}3(L)2]3+ coordination cages with structurally integral pyridyl-azo-phenyl groups can be reversibly photo-isomerised with no compositional change.
Funder
Engineering and Physical Sciences Research Council
Leverhulme Trust
Diamond Light Source
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/SC/C8SC03499K
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