Tautomerization lowers the activation barriers for N-glycosidic bond cleavage of protonated uridine and 2′-deoxyuridine
Author:
Affiliation:
1. Department of Chemistry
2. Wayne State University
3. Detroit
4. USA
Abstract
Tautomerization of [Urd+H]+ and [dUrd+H]+ greatly facilitates N-glycosidic bond cleavage.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP03620A
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