Fragmentation of a dioxolanyl radical via nonstatistical reaction dynamics: characterization of the vinyloxy radical by ns time-resolved laser flash photolysis-Reference-Cited by-同舟云学术

Fragmentation of a dioxolanyl radical via nonstatistical reaction dynamics: characterization of the vinyloxy radical by ns time-resolved laser flash photolysis

Published:2018 Issue:30 Volume:20 Page:19819-19828
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bucher Götz¹²³⁴^ORCID,Lal Mukul⁵⁶⁷⁸⁴,Rana Anup⁵⁶⁷⁸⁴,Schmittel Michael⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. Lehrstuhl für Organische Chemie II

2. Ruhr-Universität Bochum

3. 44801 Bochum

4. Germany

5. FB 8 (Chemie-Biologie)

6. Organische Chemie I

7. Universität Siegen

8. 57068 Siegen

Abstract

Photolysis of a dioxolanyl Barton ester results in formation of the vinyloxy radical, via nonstatistical reaction dynamics. The nonstatistical reaction involves ester cleavage, CO₂ loss and fragmentation of the intermediate dioxolanyl radical.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP03311K

Reference29 articles.

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4. Mechanistic Studies on RNA Strand Scission from a C2′-Radical

5. Direct Strand Scission in Double Stranded RNA via a C5-Pyrimidine Radical

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