A self-assembled coordination cage enhances the reactivity of confined amides <i>via</i> mechanical bond-twisting-Reference-Cited by-同舟云学术

A self-assembled coordination cage enhances the reactivity of confined amides via mechanical bond-twisting

Published:2022 Issue:35 Volume:24 Page:21367-21371
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tamura Hiroyuki¹²^ORCID,Takezawa Hiroki¹³^ORCID,Fujita Makoto¹³⁴,Ishikita Hiroshi¹²^ORCID

Affiliation:

1. Department of Applied Chemistry, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8654, Japan

2. Research Center for Advanced Science and Technology, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8904, Japan

3. Mitsui Link Lab Kashiwanoha 1, FS CREATION, 6-6-2 Kashiwanoha, Kashiwa, Chiba 227-0882, Japan

4. Division of Advanced Molecular Science, Institute for Molecular Science (IMS), 5-1 Higashiyama, Myodaiji, Okazaki, Aichi 444-8787, Japan

Abstract

Theoretical analysis revealed the mechanism that accelerates base-catalyzed amide hydrolysis inside the octahedral coordination cage via mechanical bond twisting as demonstrated in recent experiments.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP03126D

Reference24 articles.

1. I. V.Alabugin , Stereoelectronic Effects: A Bridge Between Structure and Reactivity , Wiley , 2016

2. A.Greenberg , C. M.Breneman and J. F.Liebman , The Amide Linkage: Selected Structural Aspects in Chemistry, Biochemistry and Materials Science , Wiley , 2000

3. Stabilization of a Cis Amide Bond in a Host−Guest Complex

4. Synthesis and structural analysis of 2-quinuclidonium tetrafluoroborate

5. Switching Pathways: Room-Temperature Neutral Solvolysis and Substitution of Amides

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