Reversible metathesis of ammonia in an acyclic germylene–Ni0 complex
Author:
Affiliation:
1. Department of Chemistry
2. Technical University Munich
3. 85747 Garching
4. Germany
5. Department of Chemical and Biological Engineering
6. University of Alabama
7. Tuscaloosa
8. USA
Abstract
Chelating single-centre ambiphile ligands based upon low-coordinate, acyclic germylenes have been developed, remaining highly Lewis acidic even when bound to Ni0, remarkably allowing for the reversible metathesis of the N–H bonds in ammonia at GeII.
Funder
Verband der Chemischen Industrie
Technische Universität München
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00450F
Reference53 articles.
1. On the Existence of a Tungsten Carbonyl Carbene Complex
2. Transition metal-carbene complexes
3. Carbenes Introduction
4. Fischer carbene complexes remain favourite targets, and vehicles for new discoveries
5. Introduction: Carbene Chemistry
Cited by 32 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Diverse Functionality of Molecular Germanium: Emerging Opportunities as Catalysts;Journal of the American Chemical Society;2024-08-22
2. Thermodynamic Modulation of Dihydrogen Activation Through Rational Ligand Design in GeII–Ni0 Complexes;Journal of the American Chemical Society;2024-08-06
3. Molecular Complexes for Catalytic Ammonia Oxidation to Dinitrogen and the Cleavage of N−H Bonds;European Journal of Inorganic Chemistry;2024-04-04
4. Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster;Chemistry – A European Journal;2024-03-04
5. Synthesis and Reactivity of Fluorenyl-Based Germanium(II) Compounds;Inorganic Chemistry;2024-01-19
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3