Unravelling highly oxidized nickel centers in the anodic black film formed during the Simons process by <i>in situ</i> X-ray absorption near edge structure spectroscopy-Reference-Cited by-同舟云学术

Unravelling highly oxidized nickel centers in the anodic black film formed during the Simons process by in situ X-ray absorption near edge structure spectroscopy

Published:2024 Issue:12 Volume:15 Page:4504-4509
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Senges Gene¹^ORCID,Buzanich Ana Guilherme²^ORCID,Lindič Tilen³,Gully Tyler A.¹^ORCID,Winter Marlon¹^ORCID,Radtke Martin²,Röder Bettina²,Steinhauer Simon¹,Paulus Beate³,Emmerling Franziska²^ORCID,Riedel Sebastian¹^ORCID

Affiliation:

1. Freie Universität Berlin, Fachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Fabeckstrasse 34/36, 14195 Berlin, Germany

2. BAM Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489 Berlin, Germany

3. Freie Universität Berlin, Fachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Theoretische Chemie, Arnimallee 22, 14195 Berlin, Germany

Abstract

The electrofluorination after Simons has been used for the last century to produce everyday life materials. An in situ XANES investigation of the controversially debated black film apparent in the Simons process revealed high-valent nickel centers.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC06081K

Reference62 articles.

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