Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere-Reference-Cited by-同舟云学术

Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere

Published:2015 Issue:27 Volume:17 Page:17914-17926
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nguyen Tran B.¹²³⁴,Bates Kelvin H.⁵²³⁴,Crounse John D.¹²³⁴,Schwantes Rebecca H.¹²³⁴,Zhang Xuan¹²³⁴,Kjaergaard Henrik G.⁶⁷⁸⁹,Surratt Jason D.¹⁰¹¹¹²⁴,Lin Peng¹³¹⁴¹⁵⁴,Laskin Alexander¹³¹⁴¹⁵⁴,Seinfeld John H.⁵²³⁴¹⁶,Wennberg Paul O.¹²³⁴¹⁶

Affiliation:

1. Division of Geological and Planetary Sciences

2. California Institute of Technology

3. Pasadena

4. USA

5. Division of Chemistry and Chemical Engineering

6. Department of Chemistry

7. University of Copenhagen

8. Copenhagen

9. Denmark

10. Department of Environmental Sciences and Engineering

11. University of North Carolina at Chapel Hill

12. Chapel Hill

13. W.R. Wiley Environmental Molecular Science Laboratory

14. Pacific Northwest National Laboratory

15. Richland

16. Division of Engineering and Applied Science

Abstract

The photooxidation of MPAN forms an energetic alkyl radical that promptly cyclizes, producing an α-lactone that participates in particle-phase chemistry.

Funder

Division of Atmospheric and Geospace Sciences

Biological and Environmental Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C5CP02001H

Reference72 articles.

1. On the observed response of ozone to NO<sub>x</sub> and VOC reactivity reductions in San Joaquin Valley California 1995–present

2. Effects of biogenic nitrate chemistry on the NO<sub>x</sub> lifetime in remote continental regions