Direct observation of long chain enrichment in flow-induced nuclei from molecular dynamics simulations of bimodal blends
Author:
Affiliation:
1. School of Mathematical Sciences, University of Nottingham
2. Nottingham
3. UK
Abstract
Modelling of flow-induced nucleation in polymers suggest that long chains are enriched in nuclei, relative to their melt concentration.
Funder
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SM/D0SM01361G
Reference53 articles.
1. A. Keller and H.Kolnaar , in Processing of Polymers , ed. H. Meijer , Wiley-VCH , Weinheim , 1997 , vol. 18, p. 189
2. Orientation-induced Nucleation in Polymer Crystallization
3. Shear-Enhanced Crystallization in Isotactic Polypropylene. 1. Correspondence between in Situ Rheo-Optics and ex Situ Structure Determination
4. Shear-Mediated Crystallization of Isotactic Polypropylene: The Role of Long Chain−Long Chain Overlap
5. Flow as an effective promotor of nucleation in polymer melts: a quantitative evaluation
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