Binuclear iron carbonyl complexes of thialene
Author:
Affiliation:
1. School of Physics and Chemistry
2. Research Center for Advanced Computation
3. Xihua University
4. Chengdu
5. China 610039
6. Department of Chemistry and Center for Computational Chemistry
7. University of Georgia
8. Athens
9. USA
Abstract
The low energy (thialene)Fe2(CO)6 structure has an η4,η4-thialene ligand bonded to two Fe(CO)3 units. The low-energy (thialene)Fe2(CO)5 structure has an η5,η3 thialene ligand bonded to an Fe2(CO)5 unit. Sulfur is not involved in ligand-metal bonding.
Funder
Division of Chemistry
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA14458F
Reference39 articles.
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3. Chemistry of the Metal Carbonyls. IV. Reactions between Certain Metal Carbonyls and Some Condensed Polycyclic Organic Systems1,2
4. Activation and desulfurization of thiophene and benzothiophene by iron carbonyls
5. New synthesis and spectroscopic studies of thialene (cyclopenta[b]thiapyran)
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