Ring opening metathesis polymerization of cyclopentene using a ruthenium catalyst confined by a branched polymer architecture

Author:

Mugemana Clément1234,Bukhryakov Konstantin V.1234,Bertrand Olivier56789,Vu Khanh B.1234,Gohy Jean-François56789,Hadjichristidis Nikos1234,Rodionov Valentin O.1234

Affiliation:

1. KAUST Catalysis Center and Division of Physical Sciences and Engineering

2. King Abdullah University of Science and Technology

3. Thuwal

4. Kingdom of Saudi Arabia

5. Université Catholique de Louvain

6. Institute of Condensed Matter and Nanosciences (IMCN)

7. Bio and soft matter (BSMA)

8. Louvain-la-Neuve

9. Belgium

Abstract

A Grubbs-type Ru alkene metathesis catalyst has been covalently anchored in the core of a globular star polymer. The spatially-confined catalyst is capable of efficient ring-opening metathesis polymerization of cyclopentene, a low-strain monomer.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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