Investigation on the interconversion from DMF-solvated to unsolvated copper(ii) pyrazolate coordination polymers

Author:

Di Nicola Corrado1234ORCID,Tombesi Alessia1234ORCID,Moroni Marco5674,Vismara Rebecca5674ORCID,Marchetti Fabio1234ORCID,Pettinari Riccardo8234ORCID,Nardo Luca5674,Vesco Guglielmo5674,Galli Simona5674ORCID,Casassa Silvia910114ORCID,Pandolfo Luciano1213144ORCID,Pettinari Claudio8234ORCID

Affiliation:

1. School of Science and Technology

2. University of Camerino

3. 62032 (MC)

4. Italy

5. Dipartimento di Scienza e Alta Tecnologia

6. Università dell'Insubria

7. 22100 Como

8. School of Pharmacy

9. Department of Chemistry

10. University of Turin

11. 10125 Torino

12. Department of Chemical Sciences

13. University of Padova

14. 35131 Padova

Abstract

Enlarging the family of CPs with the {Cu(μ-pz)2} building unit: synthesis, thermal behaviour, crystal structure and spectroscopic properties of [Cu(μ-4-Xpz)2(μ-DMF)]n (4-Xpz = 4-Xpyrazolate, X = H, Cl, Br, I) and the non-solvated counterparts.

Funder

Università degli Studi dell'Insubria

Università degli Studi di Camerino

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Reference60 articles.

1. Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments

2. G. E. Kostakis , Structural Design and Properties of Coordination Polymers , MDPI AG-Multidisciplinary Digital Publishing Institute , 2018

3. A. Morsali and L.Hashemi , Main Group Metal Coordination Polymers: Structures and Nanostructures , John Wiley & Sons , 2017

4. S. R. Batten , S. M.Neville and D. R.Turner , Coordination polymers: design, analysis and application , Royal Society of Chemistry , 2008

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