Binding of saturated and unsaturated C6-hydrocarbons to the electrophilic anion [B12Br11]−: a systematic mechanistic study-Reference-Cited by-同舟云学术

Binding of saturated and unsaturated C₆-hydrocarbons to the electrophilic anion [B₁₂Br₁₁]⁻: a systematic mechanistic study

Published:2022 Issue:36 Volume:24 Page:21759-21772
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Ma Xin¹²^ORCID,Rohdenburg Markus³^ORCID,Knorke Harald³^ORCID,Kawa Sebastian³^ORCID,Liu Judy Kuan-Yu¹,Aprà Edoardo⁴^ORCID,Asmis Knut R.³^ORCID,Azov Vladimir A.⁵^ORCID,Laskin Julia¹^ORCID,Jenne Carsten⁶^ORCID,Kenttämaa Hilkka I.¹^ORCID,Warneke Jonas³⁷^ORCID

Affiliation:

1. Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN, 47907, USA

2. School of Chemistry and Biochemistry, Georgia Institute of Technology, 901 Atlantic Drive NW, Atlanta, GA, 30332, USA

3. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, 04103, Leipzig, Germany

4. Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, WA, 99352, USA

5. Department of Chemistry, University of the Free State, PO Box 339, 9300 Bloemfontein, South Africa

6. Anorganische Chemie, Fakultät für Mathematik und Naturwissenschaften, Bergische Universität Wuppertal, 42119, Wuppertal, Germany

7. Leibniz Institute of Surface Engineering (IOM), Permoserstr. 15, D-04318, Leipzig, Germany

Abstract

Highly reactive closed-shell molecular anions [B12Br11]− spontaneously form covalent bonds with hydrocarbon molecules, including very unreactive alkanes, in the gas phase.

Funder

Purdue Research Foundation

Volkswagen Foundation

Environmental Molecular Sciences Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01042A

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