<i>Operando</i> observation of the dynamic SEI formation on a carbonaceous electrode by near-ambient pressure XPS-Reference-Cited by-同舟云学术

Operando observation of the dynamic SEI formation on a carbonaceous electrode by near-ambient pressure XPS

Published:2024 Issue: Volume: Page:
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Capone F. G.¹²³^ORCID,Sottmann J.¹²³,Meunier V.¹⁴,Pérez Ramírez L.¹²³,Grimaud A.¹⁴,Iadecola A.¹³^ORCID,Scardamaglia M.⁵^ORCID,Rueff J.-P.²⁶^ORCID,Dedryvère R.¹⁷^ORCID

Affiliation:

1. RS2E, Réseau sur le Stockage Electrochimique de l’Energie, FR CNRS 3459, France

2. Synchrotron SOLEIL, L'Orme des Merisiers, 91190 Saint-Aubin, France

3. PHENIX, Sorbonne Université, CNRS, 75005 Paris, France

4. Chimie du Solide-Energie, UMR 8260, Collège de France, 75231 Paris Cedex 05, France

5. MAX IV Laboratory, Lund University, 225 94 Lund, Sweden

6. Laboratoire de Chimie Physique-Matière et Rayonnement, Sorbonne Université, CNRS, 75005 Paris, France

7. IPREM, CNRS, Université de Pau & Pays Adour, E2S-UPPA, 64000 Pau, France

Abstract

Operando near-ambient pressure XPS was carried out on a glassy carbon electrode. For the first time, the dynamic formation of the SEI in contact with the liquid electrolyte was detected by XPS.

Funder

Horizon 2020 Framework Programme

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/EE/D3EE03228K

Reference36 articles.

1. The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model

2. Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells

3. Electronic conductivity and structure of DMSO-solvated A+ - and NR4+-graphite intercalation compounds

4. In-situ FTIR investigations on the reduction of vinylene electrolyte additives suitable for use in lithium-ion batteries

5. Nano-FTIR Spectroscopy of the Solid Electrolyte Interphase Layer on a Thin-Film Silicon Li-Ion Anode