Weakly-coordinating N-oxide and carbonyl groups for metal-catalyzed C–H activation: the case of A-ring functionalization

Author:

da Silva Júnior Eufrânio N.12345ORCID,Jardim Guilherme A. M.12345ORCID,Gomes Roberto S.67859ORCID,Liang Yu-Feng10111213ORCID,Ackermann Lutz10111213ORCID

Affiliation:

1. Institute of Exact Sciences

2. Department of Chemistry

3. Federal University of Minas Gerais

4. Belo Horizonte

5. Brazil

6. Faculty of Exact Sciences and Technologies

7. Federal University of Grande Dourados

8. Dourados

9. Department of Chemistry and Chemical Biology

10. Institut für Organische und Biomolekulare Chemie

11. Georg-August-Universität Göttingen

12. Gottingen 37077

13. Germany

Abstract

This feature review is focused on recent challenges based on the functionalizations at C-8 and C-5 positions of heterocyclic and quinoidal compounds – a topic that is still rarely explored in the literature.

Funder

Alexander von Humboldt-Stiftung

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Deutsche Forschungsgemeinschaft

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference113 articles.

1. K. C. Nicolaou and E. J.Sorensen , Classics in Total Synthesis: Targets, Strategies, Methods , Wiley , 1996

2. E. J. Corey and X.-M.Cheng , The Logic of Chemical Synthesis , John Wiley & Sons, Inc ., 1995

3. Transient Directing Groups for Transformative C–H Activation by Synergistic Metal Catalysis

4. Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

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