BaCoO2+δ: a new highly oxygen deficient perovskite-related phase with unusual Co coordination obtained by high temperature reaction with short reaction times

Author:

Waidha Aamir Iqbal12345ORCID,Zhang Hongbin6745,Lepple Maren1845ORCID,Dasgupta Supratik12945,Alff Lambert12945,Slater Peter10111213ORCID,Fortes A. D.1415161713ORCID,Clemens Oliver12345ORCID

Affiliation:

1. Technische Universität Darmstadt

2. Institut für Materialwissenschaft

3. Fachgebiet Material design durch Synthese

4. 64287 Darmstadt

5. Germany

6. Institute of Materials Science

7. TU Darmstadt

8. Eduard-Zintl-Institut für Anorganische und Physikalische Chemie

9. Fachgebiet Dünne Schichten

10. University of Birmingham

11. School of Chemistry

12. Edgbaston

13. UK

14. ISIS Facility

15. Rutherford Appleton Laboratory

16. Harwell Science and Innovation Campus

17. Didcot

Abstract

A pinch of oxygen: incorporation of small additional oxygen introduces partly square planar coordination into BaCoO2+δ.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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