2,2,3,3,3-Pentafluoro-1-propanol and its dimer: structural diversity, conformational conversion, and tunnelling motion-Reference-Cited by-同舟云学术

2,2,3,3,3-Pentafluoro-1-propanol and its dimer: structural diversity, conformational conversion, and tunnelling motion

Published:2022 Issue:24 Volume:24 Page:14975-14984
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wu Bowei¹,Seifert Nathan A.¹²,Insausti Aran¹³⁴,Ma Jiarui¹,Oswald Sönke¹⁵^ORCID,Jäger Wolfgang¹^ORCID,Xu Yunjie¹^ORCID

Affiliation:

1. Department of Chemistry, University of Alberta, 11227 Saskatchewan Drive, Edmonton, Alberta, T6G 2G2, Canada

2. Chemistry and Chemical & Biomedical Engineering Department, University of New Haven, 300 Boston Post Rd, West Haven, CT, 06516, USA

3. Departamento de Química Física, Universidad del País Vasco (UPVEHU) Barrio Sarriena s/n, Leioa, Spain

4. Instituto Biofisika (UPV/EHU, CSIC) Barrio Sarriena s/n, Leioa, Spain

5. Institut für Physikalische Chemie, Georg-August-Universität Göttingen, 37077 Göttingen, Germany

Abstract

Conformational landscapes of 2,2,3,3,3-pentafluoro-1-propanol and its hydrogen-bonded dimer were explored at the molecular level using chirped pulse Fourier transform microwave spectroscopy and ab initio calculations.

Funder

Natural Sciences and Engineering Research Council of Canada

Compute Canada

Canada Research Chairs

University of Alberta

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP01895K

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3. Microwave Spectrum of Hexafluoroisopropanol and Torsional Behavior of Molecules with a CF3–C–CF3 Group

4. The Chiral Trimer and a Metastable Chiral Dimer of Achiral Hexafluoroisopropanol: A Multi‐Messenger Study

5. Chirality Synchronization in Trifluoroethanol Dimer Revisited: The Missing Heterochiral Dimer

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