Periodic trends in trivalent actinide halides, phosphates, and arsenates

Author:

Parimi Ashutosh1ORCID,Mosher Emmalee1,Schreckenbach Georg1ORCID

Affiliation:

1. Department of Chemistry, University of Manitoba, Winnipeg, Manitoba, R3T 2N2, Canada

Abstract

Periodic trends of trivalent actinide model systems halides AnX3, AnPO4, and AnAsO4 have been explored using scalar/spin–orbit relativistic density functional theory. The trends exhibit a pre-Pu and a post-Cm behaviour, with Am acting as the switch.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference165 articles.

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3. M. S.Wickleder , B.Fourest and P. K.Dorhout , In The Chemistry of the Actinide and Transactinide Elements , Vol. 1 , Springer Netherlands , Dordrecht , 2006 , pp. 52–160

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