Ultra-low Ru-promoted CuCl2 as highly active catalyst for the hydrochlorination of acetylene-Reference-Cited by-同舟云学术

Ultra-low Ru-promoted CuCl2 as highly active catalyst for the hydrochlorination of acetylene

Published:2015 Issue:48 Volume:5 Page:38159-38163
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Xu Jiangtao¹²³⁴,Zhao Jia¹²³⁴,Zhang Tongtong¹²³⁴,Di Xiaoxia¹²³⁴,Gu Shanchuan¹²³⁴,Ni Jun¹²³⁴,Li Xiaonian¹²³⁴

Affiliation:

1. Industrial Catalysis Institute of Zhejiang University of Technology

2. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology

3. Hangzhou

4. P. R. China

Abstract

We reported a synergy between Ru and Cu, obtaining a highly active catalyst for acetylene hydrochlorination, which improved the TOF of Cu to ca. 1.81 min⁻¹ and showed that the Cu–Ru catalyst is an alternative to the toxic conventional HgCl₂ catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA03094C

Reference35 articles.

1. Reactivation of a supported gold catalyst for acetylene hydrochlorination

2. Hydrochlorination of acetylene using carbon-supported gold catalysts: A study of catalyst reactivation

3. Hydrochlorination of acetylene using gold catalysts: A study of catalyst deactivation

4. Hydrochlorination of acetylene using a supported gold catalyst: A study of the reaction mechanism

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