Nickel metallaphotoredox-catalyzed C–O bond activation/Csp<sup>2</sup>–Csp<sup>3</sup> coupling enabled by phosphine-Reference-Cited by-同舟云学术

Nickel metallaphotoredox-catalyzed C–O bond activation/Csp²–Csp³ coupling enabled by phosphine

Published:2024 Issue:11 Volume:11 Page:3058-3065
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Fang Jiaxi¹,Jian Ziheng¹,Liu Huan¹,Wang Yuting¹,Yu Xianbo¹,Mou Zehuai¹²^ORCID,Wang Huifei¹³^ORCID

Affiliation:

1. Key Laboratory of Advanced Mass Spectrometry and Molecular Analysis of Zhejiang Province, School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 315211, China

2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

3. Pingshan Translational Medicine Center, Shenzhen Bay Laboratory, Shenzhen, 518055, China

Abstract

A novel and general nickel/photoredox dual catalysis platform for benzyl alcohol C–O bond activation/Csp2–Csp3 cross coupling of benzothiazolyl bromide and free alcohol, enabled by the catalytic generation of an alkyl radical, is reported.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Natural Science Foundation of Ningbo

State Key Laboratory of Polymer Physics and Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00310A

Reference76 articles.

1. Visible light photoredox catalysis: applications in organic synthesis

2. Visible-Light Photoredox Catalysis

3. Organic Photoredox Catalysis

4. Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development

5. Photocatalytic Late-Stage C–H Functionalization