Acyl radicals generated from aldehydes with NHPI as electrocatalyst: aldehydes and alcohols as carbon-centered radical precursors-Reference-Cited by-同舟云学术

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Acyl radicals generated from aldehydes with NHPI as electrocatalyst: aldehydes and alcohols as carbon-centered radical precursors

Published:2024 Issue:17 Volume:11 Page:4842-4848
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Enríquez Rodrigo G.¹^ORCID,Dato-Santiago Juan S.¹^ORCID,del Río-Rodríguez Roberto¹^ORCID,Alemán José¹²³^ORCID,Fernández-Salas Jose A.¹²^ORCID

Affiliation:

1. Organic Chemistry Department, Módulo 2, Universidad Autónoma de Madrid, 28049 Madrid, Spain

2. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid, Madrid, Spain

3. Center for Innovation in Advanced Chemistry (ORFEO-CINQA), Universidad Autónoma de Madrid, 28049 Madrid, Spain

Abstract

We describe how N-hydroxyphthalimide (NHPI) promotes hydrogen atom transfer from aldehydes under electrochemical conditions. NHPI plays a multifunctional role, enabling the consideration of aldehydes or alcohols as sp3-carbon centered radicals.

Funder

Comunidad de Madrid

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO01067A

Reference68 articles.

1. Toward Cost-Effective Solar Energy Use

2. Key green chemistry research areas—a perspective from pharmaceutical manufacturers

3. Green chemistry and photochemistry were born at the same time

4. Organometallic C—H Bond Activation: An Introduction

5. Introduction to Selective Functionalization of C−H Bonds

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