Kinetic resolution of 2,2-disubstituted-1,3-diketones via carbene catalysis-Reference-Cited by-同舟云学术

Kinetic resolution of 2,2-disubstituted-1,3-diketones via carbene catalysis

Published:2019 Issue:3 Volume:6 Page:290-298
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xu Weici¹²³⁴⁵,Li Yuanzhen¹²³⁴⁵,Liu Rui¹²³⁴⁵,Yang Shuang¹²³⁴⁵,Liu Jian¹²³⁴⁵,Fang Xinqiang¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry

2. and Key Laboratory of Coal to Ethylene Glycol and Its Related Technology

3. Fujian Institute of Research on the Structure of Matter (FJIRSM)

4. University of Chinese Academy of Sciences

5. Fuzhou 350100

Abstract

Organocatalytic kinetic resolution of 1,3-diketones with central quaternary stereocenters was achieved for the first time. The resolution proceeds via two basic modes, and the inherent principles between the different combinations of ketone groups and the resolution patterns were also disclosed.

Funder

National Natural Science Foundation of China

Recruitment Program of Global Experts

China Postdoctoral Science Foundation

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO01137K

Reference87 articles.