Formation of [CoPt2Cl2(PPh3)4(µ3-S)2] from facile heterometallation of [Pt2(PPh3)4(µ-S)2] and its facile deheterometallation via carbonylative desulfurization to give Pt–Pt bonded [Pt2(CO)2(PPh3)2(µ-S)]-Reference-Cited by-同舟云学术

Formation of [CoPt2Cl2(PPh3)4(µ3-S)2] from facile heterometallation of [Pt2(PPh3)4(µ-S)2] and its facile deheterometallation via carbonylative desulfurization to give Pt–Pt bonded [Pt2(CO)2(PPh3)2(µ-S)]

Published:1996 Issue:20 Volume: Page:4023-4026
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Liu Huang,Tan Agnes L.,Mok Kum F.,Hor T. S. Andy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1996/DT/DT9960004023

Reference24 articles.

1. Chemistry of platinum sulphido-complexes. Part 5. Synthesis and crystal and molecular structure of 3-(η-cyclo-octa-1,5-diene)bis(µ3-sulphido)-1,1,2,2-tetrakis(triphenylphosphine)diplatinum(II)rhodium(I) hexafluorophosphate–dichloromethane (1/1), [Pt2Rh(µ3-S)2(PPh3)4(η-C8H12)]PF6·CH2Cl2

2. Chemistry of platinum sulphido-complexes. Part 6. Reactions of [Pt2(µ-S)2(PPh3)4] with the rhodium complexes [(RhL2Cl)2](L = CO or C2H4) and [Rh(2,6-Me2C6H3NC)4]PF6. Crystal and molecular structures of [Pt2Rh(µ-S)2(PPh3)4(CO)2][Rh(CO)2Cl2]·C3H6O and [Pt2Rh(µ-S)2(PPh3)4(2,6-Me2C6H3NC)2]PF6

3. Heterometallic complexes of platinum with bridging sulphido- ligands: crystal structure of [{Pt2(µ-S)2(PPh3)4}2Pd](BF4)2

4. X-Ray photoelectron spectroscopic characterization of [{Pt(PPh3)2(µ3-S)}2PtCl2], [{Pt2(PPh3)4(µ3-S)2Cu}2(µ-dppf)][PF6]2[dppf = Fe (C5H4PPh2)2] and other heterometallic aggregates derived from [{Pt(PPh3)2(µ-S)}2]

5. Synthesis and characterisation of [Ag2Pt4(μ-S)4(PPh3)8](BF4)2 · 0.25CHCl3

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