AliBu3: unprecedented main-group metal catalyst for helical sense-selective polymerization of chiral aryl isocyanides and copolymerization with achiral aryl isocyanides-Reference-Cited by-同舟云学术

AliBu3: unprecedented main-group metal catalyst for helical sense-selective polymerization of chiral aryl isocyanides and copolymerization with achiral aryl isocyanides

Published:2019 Issue:6 Volume:3 Page:1192-1198
ISSN:2052-1537
Container-title:Materials Chemistry Frontiers
language:en
Short-container-title:Mater. Chem. Front.

Author:

Wu Xiaolu¹²³⁴⁵,Yan Xinwen¹²³⁴⁵,Yang Zhi¹²³⁴⁵,Zhang Shaowen¹²³⁴⁵,Li Xiaofang¹²³⁴⁵^ORCID,Dong Yuping⁶⁷³⁸⁵,Zhi Junge¹²³⁴⁵

Affiliation:

1. Key Laboratory of Cluster Science of Ministry of Education

2. School of Chemistry and Chemical Engineering

3. Beijing Institute of Technology

4. Beijing, 100081

5. China

6. Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

7. School of Materials Science and Engineering

8. Beijing 100081

Abstract

The cationic aluminum species generated from AlⁱBu₃ and the activator [Ph₃C][B(C₆F₅)₄] serves as the first example of a main group organometallic catalyst for the coordination-insertion (co)polymerization of aryl isocyanides.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QM/C9QM00218A

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