The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts-Reference-Cited by-同舟云学术

The molecular-level effect of alkoxide additives in iron-catalyzed Kumada cross-coupling with simple ferric salts

Published:2023 Issue:10 Volume:59 Page:1317-1320
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bakas Nikki J.¹,Chourreu Pablo²³,Gayon Eric³,Lefèvre Guillaume²^ORCID,Neidig Michael L.¹⁴^ORCID

Affiliation:

1. Department of Chemistry, University of Rochester, Rochester, New York, 14627, USA

2. CNRS, Institute of Chemistry for Life and Health sciences, CSB2D, Chimie ParisTech, PSL Research University, 75005, Paris, France

3. M2i Development, Bâtiment ChemStart’Up, Allée Le Corbusier, 64170, Lacq, France

4. Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK

Abstract

Alkoxide additives promote the formation of low-coordinate homoleptic iron(ii) intermediates in cross-coupling reactions with simple iron salts.

Funder

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D2CC06257G

Reference22 articles.

1. Vinylation of Grignard reagents. Catalysis by iron

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4. Iron-Catalyzed Cross-Coupling Reactions of Alkyl-Grignard Reagents with Aryl Chlorides, Tosylates, and Triflates

5. Iron-Catalyzed Cross-Coupling of Imidoyl Chlorides with Grignard Reagents

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