The joint effect of elasticity, interaction energy and entropy on behavior of pressure- and temperature-induced electronic bistability in a family of two-dimensional Hofman-like coordination polymers

Author:

Li Ruixin1,Levchenko Georgiy12ORCID,Valverde-Muñoz Francisco Javier3ORCID,Gaspar Ana Belén3,Ivashko Victor V.4,Li Quanjun1ORCID,Xu Wei5,Fylymonov Hennagii2,Liu Bingbing1ORCID,Real José Antonio3ORCID

Affiliation:

1. State Key Laboratory of Superhard Materials, International Centre of Future Science, Jilin University, Changchun 130012, China

2. Donetsk Institute of Physics and Engineering named after A. A. Galkin, Kyiv 03028, Ukraine

3. Institut de Ciència Molecular, Departament de Química Inorgánica, Universitat de València, E-46980 València, Spain

4. Department of Correlation Optics, Chernivtsi National University, Chernivtsi 58012, Ukraine

5. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Abstract

Based on two-dimensional Hofmann-type compounds, we systematically studied the regulation of the spin state by pressure combining theory and experiments. The ways of controlling the spin state under pressure have been installed.

Funder

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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