Redox behavior of the SOFC electrode candidate NdBaMn2O5+δ investigated by high-temperature in situ neutron diffraction: first characterisation in real time of an LnBaMn2O5.5 intermediate phase

Author:

Tonus Florent1234,Bahout Mona56789,Dorcet Vincent56789,Gauthier Gilles H.10111213,Paofai Serge56789,Smith Ronald I.1415164,Skinner Stephen J.1234ORCID

Affiliation:

1. Department of Materials

2. Imperial College London

3. London SW7 2AZ

4. UK

5. Institut des Sciences Chimiques de Rennes

6. UMR CNRS 6226

7. Université de Rennes 1

8. 35042 Rennes

9. France

10. Universidad Industrial de Santander

11. Grupo INTERFASE

12. Bucaramanga

13. Colombia

14. The ISIS Facility

15. STFC Rutherford Appleton Laboratory

16. Didcot

Abstract

In situ neutron diffraction shows that hydrogen reduction of NdBaMn2O6 proceeds by forming NdBaMn2O5.5 before its conversion into NdBaMn2O5.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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