Experimental and computational diagnosis of the fluxional nature of a benzene-1,3,5-tricarboxamide-based hydrogen-bonded dimer-Reference-Cited by-同舟云学术

Experimental and computational diagnosis of the fluxional nature of a benzene-1,3,5-tricarboxamide-based hydrogen-bonded dimer

Published:2021 Issue:9 Volume:23 Page:5207-5221
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Raynal M.¹²³⁴⁵^ORCID,Li Y.¹²³⁴⁵,Troufflard C.¹²³⁴⁵,Przybylski C.¹²³⁴⁵^ORCID,Gontard G.¹²³⁴⁵,Maistriaux T.⁶⁷⁸⁹¹⁰,Idé J.⁶⁷⁸⁹¹⁰,Lazzaroni R.⁶⁷⁸⁹¹⁰^ORCID,Bouteiller L.¹²³⁴⁵^ORCID,Brocorens P.⁶⁷⁸⁹¹⁰

Affiliation:

1. Sorbonne Université

2. CNRS

3. IPCM

4. UMR 8232

5. 75252 Paris Cedex 05

6. Service de Chimie des Matériaux Nouveaux

7. Institut de Recherche sur les Matériaux

8. Université de Mons

9. Mons

10. Belgium

Abstract

High-symmetry (left) and low-symmetry (e.g. that on the right) conformations of benzene-1,3,5-tricarboxamide dimers derived from glycine alkyl esters are in rapid exchange in solution through amide/ester competition for the binding of the N–H donors.

Funder

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP06128J

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