Reduction of Eu3+ due to a change of the topological structure of the BO3 unit in borate glass-Reference-Cited by-同舟云学术

Reduction of Eu3+ due to a change of the topological structure of the BO3 unit in borate glass

Published:2015 Issue:41 Volume:44 Page:17916-17919
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Su¹²³⁴⁵,Pang Ran¹²³⁴⁵,Li Da¹²³⁴⁵,Fu Jipeng¹²³⁴⁵,Jia Yonglei¹²³⁴⁵,Li Haifeng¹²³⁴⁵,Sun Wenzhi¹²³⁴⁵,Jiang Lihong¹²³⁴⁵,Li Chengyu¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Rare Earth Resources Utilization

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022

5. P. R. China

Abstract

A reduction of Eu³⁺ into Eu²⁺ is observed in a borate glass matrix prepared under air conditions without any reductant. The remarkable reduction process is due to the changing of the topological structure of the BO₃ triangle.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT03606B

Reference36 articles.

1. Valence control, reactivity of oxygen, and catalytic activity of lanthanum strontium cobalt oxide (La2-xSrxCoO4)

2. Control of valence band potential and photocatalytic properties of NaxLa1−xTaO1+2xN2−2x oxynitride solid solutions

3. Valence State Control and Third-Order Nonlinear Optical Properties of Copper Embedded in Sodium Borosilicate Glass

4. Control of copper valence in Bi2Sr2–xCaCu2 O8

5. Multifunctional Bismuth-Doped Nanoporous Silica Glass: From Blue-Green, Orange, Red, and White Light Sources to Ultra-Broadband Infrared Amplifiers

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Dosimetric properties of Eu-doped Ca2BO3Cl;Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms;2024-03

2. Effects of rare-earth doping and reduction processes in LiCaPO4 compound: A computer simulation study;Journal of Solid State Chemistry;2022-02

3. Borate polyanions tuning persistent luminescence in Eu and Dy co-doped strontium aluminate;Materials Advances;2022

4. Color tunability of Sm3+ doped antimony–phosphate glass phosphors showing broadband fluorescence;Journal of Luminescence;2016-10