Adsorption of acrolein, propanal, and allyl alcohol on Pd(111): a combined infrared reflection–absorption spectroscopy and temperature programmed desorption study
Author:
Affiliation:
1. Fritz-Haber-Institut der Max-Planck-Gesellschaft
2. 14195 Berlin
3. Germany
4. Institut für Physikalische Chemie
5. Christian-Albrechts-Universität zu Kiel
Abstract
We present a mechanistic study on adsorption of acrolein and its partial hydrogenation products propanal and allyl alcohol over Pd(111) to understand the factors governing the selectivity in acrolein hydrogenation.
Funder
European Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP00877A
Reference45 articles.
1. Competitive CC and CO Adsorption of α-β-Unsaturated Aldehydes on Pt and Pd Surfaces in Relation with the Selectivity of Hydrogenation Reactions: A Theoretical Approach
2. Adsorption and thermal chemistry of acrolein and crotonaldehyde on Pt(111) surfaces
3. Chemoselective Catalytic Hydrogenation of Acrolein on Ag(111): Effect of Molecular Orientation on Reaction Selectivity
4. Selective hydrogenation of acrolein on supported silver catalysts: A kinetics study of particle size effects
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