Negative thermal expansion in cubic FeFe(CN)6 Prussian blue analogues

Author:

Shi Naike12345,Gao Qilong12345,Sanson Andrea6789,Li Qiang12345,Fan Longlong1011124,Ren Yang13141516,Olivi Luca17189,Chen Jun12345ORCID,Xing Xianran12345

Affiliation:

1. Beijing Advanced Innovation Center for Materials Genome Engineering

2. University of Science and Technology Beijing

3. Beijing 100083

4. China

5. Department of Physical Chemistry

6. Department of Physics and Astronomy

7. University of Padova

8. Padova I-35131

9. Italy

10. College of Physics and Materials Science

11. Tianjin Normal University

12. Tianjin 300387

13. Argonne National Laboratory

14. X-ray Science Division

15. Argonne

16. USA

17. Elettra Sincrotrone Trieste

18. 34149 Basovizza

Abstract

A new isotropic negative thermal expansion compound of FeFe(CN)6 has been found, in which the transverse vibrations of N atoms dominate in its NTE behavior.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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