Electrocatalytic proton reduction catalysed by the low-valent tetrairon-oxo cluster [Fe4(CO)10(κ2-dppn)(μ4-O)]2− [dppn = 1,1′-bis(diphenylphosphino)naphthalene]-Reference-Cited by-同舟云学术

Electrocatalytic proton reduction catalysed by the low-valent tetrairon-oxo cluster [Fe4(CO)10(κ2-dppn)(μ4-O)]2− [dppn = 1,1′-bis(diphenylphosphino)naphthalene]

Published:2015 Issue:11 Volume:44 Page:5160-5169
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghosh Shishir¹²³⁴,Holt Katherine B.¹²³⁴,Kabir Shariff E.¹⁵⁶⁷,Richmond Michael G.¹⁸⁹¹⁰,Hogarth Graeme¹²³⁴¹

Affiliation:

1. Department of Chemistry

2. University College London

3. London WC1H OAJ

4. UK

5. Jahangirnagar University

6. Dhaka-1342

7. Bangladesh

8. University of North Texas

9. Denton

10. USA

Abstract

[Fe₄(CO)₁₀(κ²-dppn)(μ₄-O)]²⁻ reduces protons and DFT calculations support the sequential formation of hydride and dihydrogen ligands at the unique iron centre.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03323J

Reference65 articles.

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