Reduction of titanocene dichloride with dysprosium: access to a stable titanocene(ii) equivalent for phosphite-free Takeda carbonyl olefination-Reference-Cited by-同舟云学术

Reduction of titanocene dichloride with dysprosium: access to a stable titanocene(ii) equivalent for phosphite-free Takeda carbonyl olefination

Published:2015 Issue:20 Volume:44 Page:9359-9362
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bousrez G.¹²³⁴,Déchamps I.¹²³⁴,Vasse J.-L.¹²³⁴,Jaroschik F.¹²³⁴

Affiliation:

1. Institut de Chimie Moléculaire

2. CNRS (UMR 7312) and Université de Reims

3. 51687 Reims Cedex 2

4. France

Abstract

A new titanocene(ii) equivalent obtained from the reduction of titanocene dichloride with dysprosium allows phosphite-free and simplified Takeda carbonyl olefination reactions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03979C

Reference23 articles.

1. The Transient Titanocene(II): Direct Synthesis from Solvated Titanium(II) Chloride and Cyclopentadienylsodium and Ensuing Interception with Diphenylacetylene as 1,1‐Bis(cyclopentadienyl)‐2,3,4,5‐tetraphenyltitanacyclopentadiene

2. Preparation and Reactions of Base-Free Bis(1,3-di-tert-butylcyclopentadienyl)titanium, Cp′2Ti, and Related Compounds

3. The Elusive Titanocene

4. The Titanocene Complex of Bis(trimethylsilyl)acetylene: Synthesis, Structure, and Chemistry

5. Synthesis of Organotitanium Complexes from Alkenes and Alkynes and Their Synthetic Applications

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