Synthesis of 3,4,5-trisubstituted phenols <i>via</i> Rh(<scp>iii</scp>)-catalyzed alkenyl C–H activation assisted by phosphonium cations-Reference-Cited by-同舟云学术

Synthesis of 3,4,5-trisubstituted phenols via Rh(iii)-catalyzed alkenyl C–H activation assisted by phosphonium cations

Published:2023 Issue:25 Volume:59 Page:3775-3778
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mao Yan¹²,Chen Wenxi¹²,Li Changchang²,Miao Lin²,Lin Yanfei²,Ling Fei¹^ORCID,Chen Zhangpei³^ORCID,Yao Jinzhong²^ORCID

Affiliation:

1. College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, China

2. College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001, Zhejiang, China

3. Center for Molecular Science and Engineering, College of Science, Northeastern University, Shenyang 110819, China

Abstract

The efficient rhodium(iii)-catalyzed coupling of phosphonium cations with internal alkynes for the construction of various 3,4,5-trisubstituted phenols is described.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Science and Technology Bureau of Jiaxing City

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00017F

Reference62 articles.

1. Transformations of Less-Activated Phenols and Phenol Derivatives via C–O Cleavage

2. Coupling without Coupling Reactions: En Route to Developing Phenols as Sustainable Coupling Partners via Dearomatization–Rearomatization Processes

3. Cross‐Dehydrogenative Coupling Reactions between Phenols and Hetarenes: Modern Trends in Cross‐Coupling Chemistry of Phenols

4. Phenol-Directed C–H Functionalization

5. Formal Direct Cross‐Coupling of Phenols with Amines

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